Which of the following explains why a teaspoon of table salt (sodium chloride) dissolved in a cup of hot water does not increase the volume of the water by an amount equal to the volume of the added salt?
  1. The crystal structure of the salt breaks down as it dissolves, decreasing the distance between individual salt particles.
  2. The ions of sodium and chloride fit between the water molecules, increasing the density of the salt- water solution.
  3. The addition of the salt decreases the surface tension of the water molecules, increasing the evaporation rate.
  4. The chloride ions released from salt as it dissolves combine with water molecules, reducing the mass of the dissolved crystals.
Explanation
Correct Response: B. When salt is dissolved in water, it forms sodium (Na+) and chloride (Cl–) ions that become essentially surrounded by water molecules. While the volume of the water does not increase, the mass of the solution does, necessarily leading to an increase in density (mass per unit volume). While the crystal structure of the salt breaks down, this does not lead to a decrease in the distance between salt molecules (A). C is incorrect because adding salt to water tends to increase its surface tension and slow the evaporation rate. The chloride ions released from the salt do not combine with water molecules (D), nor is there a decrease in the mass of the salt crystals.
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