SAT Chemistry

Category - Multiple Choice

In a galvanic cell (aka a voltaic cell), you have zinc and copper reacting. The shorthand version of these reactions is Zn|Zn+2| |Cu+2|Cu. Find the potential energy (Ecell°) of this battery.
  1. Ecell° = 0V
  2. Ecell° = -110V
  3. Ecell° =110V
  4. Ecell° = 0.42V
  5. Ecell° = -0.42V
Explanation
Answer: E. Solution is as follows:

The short hand reaction Zn|Zn+2 yields a half-reaction of Zn -> Zn+2 + 2 e-. This is an oxidation reaction because the zinc’s charge increases and it loses electrons. The corresponding half reaction for copper is Cu+2 + 2 e- -> Cu, which is a reduction reaction. The total reaction happening in this cell is:

Zn + Cu+2 --> Zn+2 + Cu

Use the equation Ecell° = Eoxidation° + Ereduction°

Look up the standard reduction potential (V) for both half reactions.

Zn --> Zn+2 + 2 e- has a V = -0.76V
Cu+2 + 2 e- --> Cu has a V = 0.34V

Adding those values yields Ecell° = -0.42V
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